Contrasting aerosol refractive index and hygroscopicity in the inflow and outflow of deep convective storms: Analysis of airborne data from DC3

Abstract

We examine three case studies during the Deep Convective Clouds and Chemistry (DC3) field experiment when storm inflow and outflow air were sampled for aerosol subsaturated hygroscopicity and the real part of refractive index (n) with a Differential Aerosol Sizing and Hygroscopicity Probe (DASH‐SP) on the NASA DC‐8. Relative to inflow aerosol particles, outflow particles were more hygroscopic (by 0.03 based on the estimated κ parameter) in one of the three storms examined. Two of three “control” flights with no storm convection reveal higher κ values, albeit by only 0.02, at high altitude (> 8 km) versus κ values in the outflow of the three storm flights are higher than predicted values (by 0.03–0.11) based on knowledge of κ values from the inflow and clear air adjacent to the storms. This suggests that other process(es) contributed to hygroscopicity enhancements such as secondary aerosol formation via aqueous‐phase chemistry. Values of n were higher in the outflow of two of the three storm flights, reaching as high as 1.54. More statistically significant differences were observed in control flights (no storms) where n decreased from 1.50–1.52 ( 8 km). Chemical data show that enhanced hygroscopicity was coincident with lower organic mass fractions, higher sulfate mass fractions, and higher O:C ratios of organic aerosol. Refractive index did not correlate as well with available chemical data. Deep convection is shown to alter aerosol radiative properties, which has implications for aerosol effects on climate.

Document Details

Document Type
Pub Defense Publication
Publication Date
Apr 27, 2017
Source ID
10.1002/2017jd026638

Entities

People

  • Alan Fried
  • Armin Sorooshian
  • Cameron R Homeyer
  • D. R. Blake
  • Douglas A. Day
  • Ewan Crosbie
  • Jose L. Jimenez
  • K. L. Thornhill
  • Luke Ziemba
  • Mary Barth
  • Pedro Campuzano-Jost
  • Taylor Shingler

Organizations

  • Institute of Arctic and Alpine Research
  • National Aeronautics and Space Administration
  • National Center for Atmospheric Research
  • Office of Naval Research
  • Universities Space Research Association
  • University of Arizona
  • University of California
  • University of Colorado Boulder
  • University of Oklahoma

Tags

Fields of Study

  • Environmental science

Readers

  • Aerosol Science/Aerosol Physics
  • Atmospheric Science/Meteorology
  • Mathematics or Statistics