Calorimetric Study with Uncertainty Analysis to Investigate the Precipitation Kinetics in a Nanostructured Al Composite

Abstract

Nanostructured Al–Zn–Mg–Cu alloy and boron carbide/Al–Zn–Mg–Cu composite powders are fabricated through cryomilling. η'‐MgZn2 precipitation in each material is characterized through differential scanning calorimetry. The activation energy of η' precipitation is derived through Kissinger analysis. The addition of boron carbide to nanostructured Al–Zn–Mg–Cu powder increases the onset and peak temperatures of η' precipitation, but do not significantly affect the activation energy. Further analysis of uncertainties in measurement indicates that weighted least squares linear regression is a more reliable method that supplements the use of differential scanning calorimetry as a method for rapid characterization of precipitation in materials.

Document Details

Document Type
Pub Defense Publication
Publication Date
Jan 30, 2018
Source ID
10.1002/adem.201700728

Entities

People

  • Blake Fullenwider
  • Julie Schoenung
  • Kaka Ma
  • Ryan Cohn

Organizations

  • Colorado State University
  • Office of Naval Research
  • University of California, Irvine

Tags

Readers

  • Computational Modeling and Simulation
  • Powder metallurgy of Titanium alloys.

Technology Areas

  • Microelectronics