3D Printing High‐Resolution Conductive Elastomeric Structures with a Solid Particle‐Free Emulsion Ink

Abstract

Fabricating complex structures on micro‐ and mesoscales is a critical aspect in the design of advanced sensors and soft electronics. However, soft lithographic methods offer an important approach to fabricating such structures, the progress in the field of additive manufacturing (e.g., 3D printing) offers methods of fabrication with much more material complexity. The rheological complexity of the printing material, however, often dictates the limitations of printing. In particular, the challenges involved in synthesizing printing materials that can enable shape retention at smaller scales (<100 μm), yet be conductive, limits many applications of 3D printing to soft microelectronics. Herein, a printing‐centered approach using a novel particle‐free conductive emulsion ink is presented. This approach separates the printing and polymerization of a conductive monomer (pyrrole) and renders a novel ink that is used to print filaments with heretofore impossible to realize 3D feature dimensions and build structures with high shape retention. The printability of the ink is evaluated, and post‐treatment properties assessed. Multidirectional strain sensors are printed using the emulsion ink to illustrate an exemplary application in soft electronics.

Document Details

Document Type
Pub Defense Publication
Publication Date
Aug 18, 2021
Source ID
10.1002/adem.202100902

Entities

People

  • Chen Wang
  • Gaurav Chaudhary
  • Ralph Nuzzo
  • Randy H. Ewoldt

Organizations

  • Harvard University
  • National Science Foundation
  • Royal Institute of Technology
  • University of Illinois Urbana–Champaign

Tags

Fields of Study

  • Materials science

Readers

  • Nanoscale Plasmonic Nanotechnology
  • Polymer Science and Technology
  • Systems Analysis and Design

Technology Areas

  • Microelectronics