Gilding with Graphene: Rapid Chemical Vapor Deposition Synthesis of Graphene on Thin Metal Leaves

Abstract

Gilding is the ancient process of coating intricate artifacts with precious metals. Fascinating Egyptian and Chinese sculptures, coated with −1). Mathematical models of growth kinetics guide the development of extremely rapid synthesis conditions, resulting in the formation of high‐quality graphene on Pd in less than a minute, owing to the graphene grains growing twice as fast as copper‐catalyzed growth. The graphene monolayer on the leaf increases the effective surface modulus by 59% to 236 GPa. Uniaxial strain testing with Raman spectroscopy reveals the excellent crystallinity of graphene by probing the stress‐induced phonon shifts. This new material could open exciting opportunities in utilizing high‐quality 2D materials to coat large structures.

Document Details

Document Type
Pub Defense Publication
Publication Date
Sep 06, 2018
Source ID
10.1002/adfm.201804068

Entities

People

  • Charalampos Androulidakis
  • Kaihao Zhang
  • Mingze Chen
  • Sameh Tawfick

Organizations

  • Office of Naval Research
  • University of Illinois Urbana–Champaign

Tags

Fields of Study

  • Physics

Readers

  • Aerospace Research.
  • Educational Psychology
  • Thin Film Deposition Science.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene