Bioencapsulated MXene Flakes for Enhanced Stability and Composite Precursors
Abstract
Here it is shown that Ti3C2Tx MXene flakes can be co‐assembled with recombinant silk fibroin in aqueous suspensions with silk fibroin nanolayers uniformly covering individual flakes. These bioencapsulated flakes evolve with time due to the gradual growth of silk bundles having β‐sheet secondary organization with unique nanofibrillar morphologies extending across flake edges and forming long fringes around individual MXene flakes. This spontaneous reorganization of recombinant silk suggests surface template‐initiated formation of intramolecular hydrogen bonding of silk backbones assisted by intermolecular electrostatic and hydrogen bonding with the MXene flake. The formation of dense and hydrophobic β‐sheets results in development of a protective shell that hinders the surface oxidation of Ti3C2Tx in colloidal solution in water and significantly extends the storage life of the individual MXene flakes. Moreover, assembly into organized laminated composites with individual bioencapsulated flakes tightly interconnected via biopolymer bundles and hairs produces robust freestanding electrically conductive membranes with enhanced transport properties.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Sep 09, 2020
- Source ID
- 10.1002/adfm.202004554
Entities
People
- Christine B. Hatter
- Daria Bukharina
- Michelle C. Krecker
- Vladimir V. Tsukruk
- Yury Gogotsi
Organizations
- Air Force Office of Scientific Research
- Drexel University
- Georgia Tech
- National Science Foundation