Enhancing Performance of Nonfullerene Acceptors via Side‐Chain Conjugation Strategy
Abstract
A side‐chain conjugation strategy in the design of nonfullerene electron acceptors is proposed, with the design and synthesis of a side‐chain‐conjugated acceptor (ITIC2) based on a 4,8‐bis(5‐(2‐ethylhexyl)thiophen‐2‐yl)benzo[1,2‐b:4,5‐b′]di(cyclopenta‐dithiophene) electron‐donating core and 1,1‐dicyanomethylene‐3‐indanone electron‐withdrawing end groups. ITIC2 with the conjugated side chains exhibits an absorption peak at 714 nm, which redshifts 12 nm relative to ITIC1. The absorption extinction coefficient of ITIC2 is 2.7 × 105m−1 cm−1, higher than that of ITIC1 (1.5 × 105m−1 cm−1). ITIC2 exhibits slightly higher highest occupied molecular orbital (HOMO) (−5.43 eV) and lowest unoccupied molecular orbital (LUMO) (−3.80 eV) energy levels relative to ITIC1 (HOMO: −5.48 eV; LUMO: −3.84 eV), and higher electron mobility (1.3 × 10−3 cm2 V−1 s−1) than that of ITIC1 (9.6 × 10−4 cm2 V−1 s−1). The power conversion efficiency of ITIC2‐based organic solar cells is 11.0%, much higher than that of ITIC1‐based control devices (8.54%). Our results demonstrate that side‐chain conjugation can tune energy levels, enhance absorption, and electron mobility, and finally enhance photovoltaic performance of nonfullerene acceptors.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Jul 17, 2017
- Source ID
- 10.1002/adma.201702125
Entities
People
- Cenqi Yan
- Jiayu Wang
- Qianqian Zhang
- Wei Ma
- Wei Wang
- Wei You
- Xiaohui Wang
- Xiaowei Zhan
- Yang Wu
Organizations
- Ministry of Science and Technology of the People's Republic of China
- National Natural Science Foundation of China
- National Science Foundation
- Office of Naval Research
- Peking University
- United States Department of Energy
- University of North Carolina at Chapel Hill
- Xi'an Jiaotong University