Solution Mask Liquid Lithography (SMaLL) for One‐Step, Multimaterial 3D Printing

Abstract

A novel methodology for printing 3D objects with spatially resolved mechanical and chemical properties is reported. Photochromic molecules are used to control polymerization through coherent bleaching fronts, providing large depths of cure and rapid build rates without the need for moving parts. The coupling of these photoswitches with resin mixtures containing orthogonal photo‐crosslinking systems allows simultaneous and selective curing of multiple networks, providing access to 3D objects with chemically and mechanically distinct domains. The power of this approach is showcased through the one‐step fabrication of bioinspired soft joints and mechanically reinforced “brick‐and‐mortar” structures.

Document Details

Document Type
Pub Defense Publication
Publication Date
Jun 21, 2018
Source ID
10.1002/adma.201800364

Entities

People

  • Craig Hawker
  • David P. Bothman
  • Evan Callaway
  • Fabian Eisenreich
  • Frank W. Zok
  • Neil Dolinski
  • Roberto Chavez
  • Ronnie V. Garcia
  • Stefan Hecht
  • Zachariah A Page

Organizations

  • Humboldt-Universität zu Berlin
  • National Science Foundation
  • University of California
  • University of California, Santa Barbara

Tags

Readers

  • Computational Fluid Dynamics (CFD)
  • Polymer Science and Technology
  • Reinforced Composite Materials

Technology Areas

  • Biotechnology