Bioinspired Hydrogel Interferometer for Adaptive Coloration and Chemical Sensing

Abstract

Living organisms ubiquitously display colors that adapt to environmental changes, relying on the soft layer of cells or proteins. Adoption of soft materials into an artificial adaptive color system has promoted the development of material systems for environmental and health monitoring, anti‐counterfeiting, and stealth technologies. Here, a hydrogel interferometer based on a single hydrogel thin film covalently bonded to a reflective substrate is reported as a simple and universal adaptive color platform. Similar to the cell or protein soft layer of color‐changing animals, the soft hydrogel layer rapidly changes its thickness in response to external stimuli, resulting in instant color change. Such interference colors provide a visual and quantifiable means of revealing rich environmental metrics. Computational model is established and captures the key features of hydrogel stimuli‐responsive swelling, which elucidates the mechanism and design principle for the broad‐based platform. The single material–based platform has advantages of remarkable color uniformity, fast response, high robustness, and facile fabrication. Its versatility is demonstrated by diverse applications: a volatile‐vapor sensor with highly accurate quantitative detection, a colorimetric sensor array for multianalyte recognition, breath‐controlled information encryption, and a colorimetric humidity indicator. Portable and easy‐to‐use sensing systems are demonstrated with smartphone‐based colorimetric analysis.

Document Details

Document Type
Pub Defense Publication
Publication Date
Apr 11, 2018
Source ID
10.1002/adma.201800468

Entities

People

  • Dipika Sikka
  • Hang Jerry Qi
  • Meng Qin
  • Mo Sun
  • Ruobing Bai
  • Xiaoshi Qian
  • Ximin He
  • Yiqi Mao
  • Yuan Zhao
  • Zhigang Suo

Organizations

  • Georgia Tech
  • Harvard University
  • National Science Foundation
  • Office of Naval Research
  • UCLA Henry Samueli School of Engineering and Applied Science
  • University of California, Los Angeles

Tags

Readers

  • Nanoscale Plasmonic Nanotechnology
  • Systems Analysis and Design

Technology Areas

  • Biotechnology