Heterogeneous Electronic and Photonic Devices Based on Monolayer Ternary Telluride Core/Shell Structures

Abstract

Device engineering based on the tunable electronic properties of ternary transition metal dichalcogenides has recently gained widespread research interest. In this work, monolayer ternary telluride core/shell structures are synthesized using a one‐step chemical vapor deposition process with rapid cooling. The core region is the tellurium‐rich WSe2−2xTe2x alloy, while the shell is the tellurium‐poor WSe2−2yTe2y alloy. The bandgap of the material is ≈1.45 eV in the core region and ≈1.57 eV in the shell region. The lateral gradient of the bandgap across the monolayer heterostructure allows for the fabrication of heterogeneous transistors and photodetectors. The difference in work function between the core and shell regions leads to a built‐in electric field at the heterojunction. As a result, heterogeneous transistors demonstrate a unidirectional conduction and strong photovoltaic effect. The bandgap gradient and high mobility of the ternary telluride core/shell structures provide a unique material platform for novel electronic and photonic devices.

Document Details

Document Type
Pub Defense Publication
Publication Date
Oct 14, 2020
Source ID
10.1002/adma.202002548

Entities

People

  • Ankit Sharma
  • Junzhe Kang
  • Kai Xu
  • Wenjuan Zhu
  • Xiaoqiao Hu
  • Zheng Hao

Organizations

  • National Science Foundation
  • Office of Naval Research
  • University of Illinois Urbana–Champaign

Tags

Fields of Study

  • Materials science

Readers

  • Nanoscale Plasmonic Nanotechnology
  • Quantum Dot Semiconductor Device Photonics and Graphene Optoelectronic Materials and THz Physics.
  • Solar Photovoltaics and Thermoelectric Devices.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene