Structural Insight in the Interfacial Effect in Ferroelectric Polymer Nanocomposites
Abstract
Both experimental results and theoretical models suggest the decisive role of the filler–matrix interfaces on the dielectric, piezoelectric, pyroelectric, and electrocaloric properties of ferroelectric polymer nanocomposites. However, there remains a lack of direct structural evidence to support the so‐called interfacial effect in dielectric nanocomposites. Here, a chemical mapping of the interfacial coupling between the nanofiller and the polymer matrix in ferroelectric polymer nanocomposites by combining atomic force microscopy–infrared spectroscopy (AFM–IR) with first‐principles calculations and phase‐field simulations is provided. The addition of ceramic fillers into a ferroelectric polymer leads to augmentation of the local conformational disorder in the vicinity of the interface, resulting in the local stabilization of the all‐trans conformation (i.e., the polar β phase). The formation of highly polar and inhomogeneous interfacial regions, which is further enhanced with a decrease of the filler size, has been identified experimentally and verified by phase‐field simulations and density functional theory (DFT) calculations. This work offers unprecedented structural insights into the configurational disorder‐induced interfacial effect and will enable rational design and molecular engineering of the filler–matrix interfaces of electroactive polymer nanocomposites to boost their collective properties.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Nov 04, 2020
- Source ID
- 10.1002/adma.202005431
Entities
People
- Bing Zhang
- J. Bernholc
- Li Li
- Long‐qing Chen
- Qing Wang
- Seong H Kim
- Teague Williams
- Tiannan Yang
- Wenchang Lu
- Yang Liu
- Yao Zhou
- Yen‐ting Lin
Organizations
- Air Force Office of Scientific Research
- National Science Foundation
- North Carolina State University
- Office of Naval Research
- Pennsylvania State University