High Toughness in Ultralow Density Graphene Oxide Foam

Abstract

Here, the scalable synthesis of low‐density 3D macroscopic structure of graphene oxide (GO) interconnected with polydimethylsiloxane (PDMS) is reported. A controlled amount of PDMS is infused into the freeze‐dried foam to result into a very rigid structure with improved mechanical properties, such as tensile plasticity and toughness. The PDMS wets the graphene oxide sheets and acts like glue between the 2D sheets. Molecular dynamics simulations are used to further elucidate the mechanisms of the interactions of graphene oxide layers with PDMS. The ability of using the interconnecting graphene oxide foam as an effective oil–water separator and stable insulating behavior to elevated temperatures are further demonstrated. The structural rigidity of the sample is also tested using laser impact and compared with GO foam.

Document Details

Document Type
Pub Defense Publication
Publication Date
Mar 07, 2017
Source ID
10.1002/admi.201700030

Entities

People

  • Bingqing Wei
  • Chandra Sekhar Tiwary
  • Cristiano F. Woellner
  • Douglas S. Galvao
  • James Tour
  • Jun Lou
  • Luong Xuan Duy
  • Peter Samora Owuor
  • Pulickel Ajayan
  • Robert Vajtai
  • Rodrigo V. Salvatierra
  • Sanjit Bhowmick
  • Sehmus Ozden
  • Soumya Vinod
  • Suppanat Kosolwattana
  • Syed A. S. Asif
  • Tong Li

Organizations

  • Air Force Office of Scientific Research
  • Rice University
  • São Paulo Research Foundation
  • University of Campinas
  • University of Delaware

Tags

Fields of Study

  • Physics

Readers

  • Aerosol Science/Aerosol Physics
  • Nanocomposite Materials Science
  • Reinforced Composite Materials

Technology Areas

  • Directed Energy
  • Microelectronics
  • Microelectronics - Graphene