Hydrogel‐Based Additive Manufacturing of Lithium Cobalt Oxide
Abstract
3D multicomponent metal oxides with complex architectures can enable previously impossible energy storage devices, particularly lithium‐ion battery (LIB) electrodes with fully controllable form factors. Existing additive manufacturing approaches for fabricating 3D multicomponent metal oxides rely on particle‐based or organic–inorganic binders, which are limited in their resolution and chemical composition, respectively. In this work, aqueous metal salt solutions are used as metal precursors to circumvent these limitations, and provide a platform for 3D printing multicomponent metal oxides. As a proof‐of‐concept, architected lithium cobalt oxide (LCO) structures are fabricated by first synthesizing a homogenous lithium and cobalt nitrate aqueous photoresin, and then using it with digital light processing printing to obtain lithium and cobalt ion containing hydrogels. The 3D hydrogels are calcined to obtain micro‐porous self‐similar LCO architectures with a resolution of ≈100 µm. These free‐standing, binder‐ and conductive additive‐free LCO structures are integrated as cathodes into LIBs, and exhibit electrochemical capacity retention of 76% over 100 cycles at C/10. This facile approach to fabricating 3D LCO structures can be extended to other materials by tailoring the identity and stoichiometry of the metal salt solutions used, providing a versatile method for the fabrication of multicomponent metal oxides with complex 3D architectures.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Nov 11, 2020
- Source ID
- 10.1002/admt.202000791
Entities
People
- Daryl W Yee
- Julia R. Greer
- Max A. Saccone
- Michael A. Citrin
- Victoria L. Tovmasyan
- Zane W. Taylor
Organizations
- California Institute of Technology
- National Institutes of Health
- United States Department of Defense
- University of California