Self‐Regulative Direct Ink Writing of Frontally Polymerizing Thermoset Polymers
Abstract
The ability to manufacture highly intricate designs is one of the key advantages of 3D printing. Achieving high dimensional accuracy requires precise, often time‐consuming calibration of the process parameters. Computerized feedback control systems for 3D printing enable sensing and real‐time adaptation and optimization of these parameters at every stage of the print, but multiple challenges remain with sensor embedment and measurement accuracy. In contrast to these active control approaches, here, the authors harness frontal polymerization (FP) to rapidly cure extruded filament in tandem with the printing process. A temperature gradient present along the filament, which is dependent on the printing parameters, can impose control over this exothermic reaction. Experiments and theory reveal a self‐regulative mechanism between filament temperature and cure kinetics that allows the frontal cure speed to autonomously match the print speed. This self‐regulative printing process rapidly adapts to changes in print speed and environmental conditions to produce complex, high‐fidelity structures and freestanding architectures spanning up to 100 mm, greatly expanding the capabilities of direct ink writing (DIW).
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Apr 27, 2022
- Source ID
- 10.1002/admt.202200230
Entities
People
- Arif Z Nelson
- Jia En Aw
- Leon M Dean
- Mostafa Yourdkhani
- Nancy Sottos
- Philippe H Geubelle
- Randy H. Ewoldt
- Xiang Zhang
Organizations
- Air Force Office of Scientific Research
- Colorado State University
- National Science Foundation
- University of Illinois Urbana–Champaign
- University of Wyoming