High‐Efficiency Polymer:Nonfullerene Solar Cells with Quaterthiophene‐Containing Polyimide Interlayers
Abstract
Interfacial layers (interlayers) are one of the emerging approaches in organic solar cells with bulk heterojunction (BHJ) layers because the solar cell efficiency can be additionally improved by their presence. However, less attention is paid to the use of interlayers for polymer:nonfullerene solar cells, which have strong advantages over polymer:fullerene solar cells. In addition, most polymers used for the interlayers possess a low glass transition temperature (Tg). Here, it is demonstrated that two types of quarterthiophene‐containing polyimides (PIs) with high Tg (>198 °C), which are synthesized using pyromellitic dianhydride (PMDA) and cyclobutane‐1,2,3,4‐tetracarboxylic dianhydride (CTCDA), can act as an interfacial layer in the polymer:nonfullerene solar cells with the BHJ layers of poly[(2,6‐(4,8‐bis(5‐(2‐ethylhexyl)thiophen‐2‐yl)‐benzo[1,2‐b:4,5‐b′]dithiophene))‐alt‐(5,5‐(1′,3′‐di‐2‐thienyl‐5′,7′‐bis(2‐ethylhexyl)benzo[1′,2′‐c:4′,5′‐c′]dithiophene‐4,8‐dione))] (PBDB‐T) and 3,9‐bis(2‐methylene(3‐(1,1‐dicyanomethylene)‐indanone))‐5,5,11,11‐tetrakis(4‐hexylphenyl)‐dithieno[2,3‐d:2′,3′‐d′]‐s‐indaceno[1,2‐b:5,6‐b′]dithiophene) (ITIC), or (3‐(1,1‐dicyanomethylene)‐1‐methyl‐indanone)‐5,5,11,11‐tetrakis(4‐hexylphenyl)‐dithieno[2,3‐d:2′,3′‐d′]‐s‐indaceno[1,2‐b:5,6‐b′]‐dithiophene) (IT‐M). Interestingly, the efficiency and stability of devices are improved by the PMDA‐based PI interlayers with a stretched chain structure but degraded by the CTCDA‐based PI interlayers with a bended chain structure.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Jun 10, 2018
- Source ID
- 10.1002/advs.201800331
Entities
People
- Euyoung Park
- Hwajeong Kim
- Hyemi Han
- Jooyeok Seo
- Youngkyoo Kim
Organizations
- Air Force Office of Scientific Research
- Kyungpook National University
- National Research Foundation of Korea