An Areal‐Energy Standard to Validate Air‐Breathing Electrodes for Rechargeable Zinc–Air Batteries

Abstract

Rechargeable zinc–air batteries may become safe, sustainable, low‐cost, and energy‐dense alternatives to Li‐ion batteries for many applications, but problems associated with today's air‐breathing electrodes limit zinc–air performance. To overcome this challenge, researchers have investigated hundreds of air‐breathing electrode variations over the last decade. Unfortunately, the efficacy of these variations remains ambiguous due to nonstandardized cycling protocols that map to areal‐energy values spanning five orders of magnitude. To compete with Li‐ion batteries, researchers should cycle zinc–air cells at 35 mWh cmgeo−2, but only 8, of the 100 publications reviewed here, breach this threshold. Once the community cycles zinc–air cells at the proposed areal energy and better understands failure mechanisms, lab‐scale results will translate to practical advancements.

Document Details

Document Type
Pub Defense Publication
Publication Date
Jun 22, 2020
Source ID
10.1002/aenm.202001287

Entities

People

  • Brandon J Hopkins
  • Christopher N Chervin
  • Debra R. Rolison
  • Jeffrey W Long
  • Joseph F Parker

Organizations

  • National Academies of Sciences, Engineering, and Medicine
  • Office of Naval Research
  • United States Naval Research Laboratory

Tags

Readers

  • Educational Psychology
  • Nanoscale Plasmonic Nanotechnology
  • Systems Analysis and Design