The Path to 20% Power Conversion Efficiencies in Nonfullerene Acceptor Organic Solar Cells

Abstract

The power conversion efficiencies (PCEs) of single‐junction organic solar cells (OSC) have now reached over 18%. This rapid recent progress can be attributed to the development of new nonfullerene electron acceptors (NFAs) that are paired with suitable high performing polymer electron donors. Substantial improvements in the PCEs and long‐term stability enabled by NFA OSCs have allowed the development and integration of these systems into many niche and novel applications. Here, the recent progress that has been made in understanding the device photophysics of high performing polymer:NFA blends is highlighted. As the bulk heterojunction morphology is intrinsically linked to the device photophysics, this review focuses on studies that have provided noteworthy morphological insights using advanced techniques such as solid‐state NMR and resonant soft X‐ray scattering. Through this, some of the major challenges that must be overcome to attain PCEs of over 20% in NFA OSCs are addressed.

Document Details

Document Type
Pub Defense Publication
Publication Date
Dec 18, 2020
Source ID
10.1002/aenm.202003441

Entities

People

  • Akchheta Karki
  • Alexander J Gillett
  • Richard Friend
  • Thuc-Quyen Nguyen

Organizations

  • Office of Naval Research
  • Simons Foundation
  • University of California, Santa Barbara
  • University of Cambridge

Tags

Fields of Study

  • Materials science

Readers

  • Economics
  • Polymer Science and Technology
  • Solar Photovoltaics and Thermoelectric Devices.

Technology Areas

  • Microelectronics