Room‐Temperature Sodium–Sulfur Batteries and Beyond: Realizing Practical High Energy Systems through Anode, Cathode, and Electrolyte Engineering
Abstract
The increasing energy demands of society today have led to the pursuit of alternative energy storage systems that can fulfil rigorous requirements like cost‐effectiveness and high storage capacities. Based fundamentally on earth‐abundant sodium and sulfur, room‐temperature sodium–sulfur batteries are a promising solution in applications where existing lithium‐ion technology remains less economically viable, particularly in large‐scale stationary systems such as grid‐level storage. Here, the key challenges in the field are first highlighted, followed by comprehensive analyses of accessible strategies to overcome them, starting from engineering of the anode–electrolyte interface in both liquid and solid electrolytes. Recently reported polymer and solid‐state electrolytes are also surveyed. Thereafter, the core principles guiding use‐inspired design of cathode architectures, covering the spectrum of elemental sulfur and polysulfide cathodes, to emerging host structures, and covalent composites are focused upon. Future prospects are explored, with insights into other alkali‐metal systems beyond sodium–sulfur batteries, such as the potassium–sulfur battery. Finally a conclusion is provided by outlining the research directions necessary to attain high energy sodium–sulfur devices, and potential solutions to issues concerning large‐scale production, so as to ultimately realize widespread deployment of practical energy storage systems.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Feb 19, 2021
- Source ID
- 10.1002/aenm.202003493
Entities
People
- Alex Yong Sheng Eng
- Jianmin Luo
- Vipin Kumar
- Weiyang Li
- Wenyu Wang
- Yiwen Zhang
- Yongming Sun
- Zhi Wei Seh
Organizations
- Air Force Office of Scientific Research
- Dartmouth College
- Huazhong University of Science and Technology
- Indian Institute of Technology Delhi
- Institute of Materials Research and Engineering
- National Research Foundation