A Highly Stable Zeotype Mesoporous Zirconium Metal–Organic Framework with Ultralarge Pores
Abstract
Through topological rationalization, a zeotype mesoporous Zr‐containing metal–organic framework (MOF), namely PCN‐777, has been designed and synthesized. PCN‐777 exhibits the largest cage size of 3.8 nm and the highest pore volume of 2.8 cm3 g−1 among reported Zr‐MOFs. Moreover, PCN‐777 shows excellent stability in aqueous environments, which makes it an ideal candidate as a support to incorporate different functional moieties. Through facile internal surface modification, the interaction between PCN‐777 and different guests can be varied to realize efficient immobilization.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Nov 10, 2014
- Source ID
- 10.1002/ange.201409334
Entities
People
- Andrey Yakovenko
- Dawei Feng
- Hong‐cai Zhou
- Jie Su
- Jihye Park
- Kecheng Wang
- Mathieu Bosch
- Tian‐fu Liu
- Xiaodong Zou
- Zhangwen Wei
Organizations
- Knut and Alice Wallenberg Foundation
- Office of Basic Energy Sciences
- Office of Naval Research
- Swedish Research Council
- United States Department of Energy