3,6‐Dinitropyrazolo[4,3‐c]pyrazole‐Based Multipurpose Energetic Materials through Versatile N‐Functionalization Strategies
Abstract
A family of 3,6‐dinitropyrazolo[4,3‐c]pyrazole‐based energetic compounds was synthesized by using versatile N‐functionalization strategies. Subsequently, nine ionic derivatives of the N,N′‐(3,6‐dinitropyrazolo[4,3‐c]pyrazole‐1,4‐diyl)dinitramidate anion were prepared by acid‐base reactions and fully characterized by infrared, multinuclear NMR spectra, and elemental analysis. The structures of four of these compounds were further confirmed by single‐crystal X‐ray diffraction. Based on their different physical and detonation properties, these compounds exhibit promising potential as modern energetic materials and can be variously classified as green primary explosives, high‐performance secondary explosives, fuel‐rich propellants, and propellant oxidizers.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Sep 15, 2016
- Source ID
- 10.1002/ange.201606894
Entities
People
- Damon A. Parrish
- Jean'ne Shreeve
- Jiaheng Zhang
- Lauren A. Mitchell
- Ping Yin
Organizations
- CFD Research Corporation (United States)
- Defense Threat Reduction Agency
- Harbin Institute of Technology
- Japan Society for the Promotion of Science
- M J Murdock Charitable Trust
- Office of Naval Research
- United States Naval Research Laboratory
- University of Idaho
- University of Minnesota
- Yokohama National University