Two‐Dimensional Fullerene Assembly from an Exfoliated van der Waals Template
Abstract
Two‐dimensional (2D) materials are commonly prepared by exfoliating bulk layered van der Waals crystals. The creation of synthetic 2D materials from bottom‐up methods is an important challenge as their structural flexibility will enable chemists to tune the materials properties. A 2D material was assembled using C60 as a polymerizable monomer. The C60 building blocks are first assembled into a layered solid using a molecular cluster as structure director. The resulting hierarchical crystal is used as a template to polymerize its C60 monolayers, which can be exfoliated down to 2D crystalline nanosheets. Derived from the parent template, the 2D structure is composed of a layer of inorganic cluster, sandwiched between two monolayers of polymerized C60. The nanosheets can be transferred onto solid substrates and depolymerized by heating. Electronic absorption spectroscopy reveals an optical gap of 0.25 eV, narrower than that of the bulk parent crystalline solid.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Apr 27, 2018
- Source ID
- 10.1002/ange.201800953
Entities
People
- Andrew C Crowther
- Bonnie Choi
- Ilan Jen‐la Plante
- Jonathan Owen
- Kihong Lee
- Maria V. Paley
- Xavier Roy
- Xiaoyang Zhu
- Xinjue Zhong
Organizations
- Air Force Office of Scientific Research
- Barnard College
- Columbia University
- National Science Foundation