Frequency‐Driven Self‐Organized Helical Superstructures Loaded with Mesogen‐Grafted Silica Nanoparticles
Abstract
Adding colloidal nanoparticles into liquid‐crystal media has become a promising pathway either to enhance or to introduce novel properties for improved device performance. Here we designed and synthesized new colloidal hybrid silica nanoparticles passivated with a mesogenic monolayer on the surface to facilitate their organo‐solubility and compatibility in a liquid‐crystal host. The resulting nanoparticles were identified by 1H NMR spectroscopy, TEM, TGA, and UV/Vis techniques, and the hybrid nanoparticles were doped into a dual‐frequency cholesteric liquid‐crystal host to appraise both their compatibility with the host and the effect of the doping concentration on their electro‐optical properties. Interestingly, the silica‐nanoparticle‐doped liquid‐crystalline nanocomposites were found to be able to dynamically self‐organize into a helical configuration and exhibit multi‐stability, that is, homeotropic (transparent), focal conic (opaque), and planar states (partially transparent), depending on the frequency applied at sustained low voltage. Significantly, a higher contrast ratio between the transparent state and scattering state was accomplished in the nanoparticle‐embedded liquid‐crystal systems.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Oct 06, 2016
- Source ID
- 10.1002/anie.201606895
Entities
People
- Guoqiang Li
- Hari K. Bisoyi
- Karla G. Gutierrez‐cuevas
- Ling Wang
- Loon‐seng Tan
- Quan Li
- Richard A. Vaia
- Zhi‐gang Zheng
Organizations
- Air Force Research Laboratory
- Kent State University
- National Institutes of Health
- Ohio State University