Multi‐Step Crystallization of Barium Carbonate: Rapid Interconversion of Amorphous and Crystalline Precursors
Abstract
The direct observation of amorphous barium carbonate (ABC), which transforms into a previously unknown barium carbonate hydrate (herewith named gortatowskite) within a few hundred milliseconds of formation, is described. In situ X‐ray scattering, cryo‐, and low‐dose electron microscopy were used to capture the transformation of nanoparticulate ABC into gortatowskite crystals, highly anisotropic sheets that are up to 1 μm in width, yet only about 10 nm in thickness. Recrystallization of gortatowskite to witherite starts within 30 seconds. We describe a bulk synthesis and report a first assessment of the composition, vibrational spectra, and structure of gortatowskite. Our findings indicate that transient amorphous and crystalline precursors can play a role in aqueous precipitation pathways that may often be overlooked owing to their extremely short lifetimes and small dimensions. However, such transient precursors may be integral to the formation of more stable phases.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Nov 15, 2017
- Source ID
- 10.1002/anie.201709526
Entities
People
- Derk Joester
- Hasti Asayesh‐ardakani
- Michael L Whittaker
- Paul J M Smeets
- Reza Shahbazian‐yassar
Organizations
- Argonne National Laboratory
- Army Research Office
- Division of Materials Research
- National Science Foundation
- Northwestern University
- University of Illinois at Chicago