4D‐Printing of Photoswitchable Actuators
Abstract
Shape‐switching behavior, where a transient stimulus induces an indefinitely stable deformation that can be recovered on exposure to another transient stimulus, is critical to building smart structures from responsive polymers as continue power is not needed to maintain deformations. Herein, we 4D‐print shape‐switching liquid crystalline elastomers (LCEs) functionalized with supramolecular crosslinks, dynamic covalent crosslinks, and azobenzene. The salient property of shape‐switching LCEs is that light induces long‐lived, deformation that can be recovered on‐demand by heating. UV‐light isomerizes azobenzene from trans to cis, and temporarily breaks the supramolecular crosslinks, resulting in a programmed deformation. After UV, the shape‐switching LCEs fix more than 90 % of the deformation over 3 days by the reformed supramolecular crosslinks. Using the shape‐switching properties, we print Braille‐like actuators that can be photoswitched to display different letters. This new class of photoswitchable actuators may impact applications such as deployable devices where continuous application of power is impractical.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Jan 12, 2021
- Source ID
- 10.1002/anie.202012618
Entities
People
- Cedric P. Ambulo
- Hyun Kim
- Kyle Searles
- Laura K. Rivera‐tarazona
- Suitu Wang
- Taylor H. Ware
- Xili Lu
Organizations
- Air Force Office of Scientific Research
- National Science Foundation Directorate for Mathematical & Physical Sciences
- Sichuan University
- United States Army Combat Capabilities Development Command
- University of Texas at Dallas