Ultrasound‐Responsive Aqueous Two‐Phase Microcapsules for On‐Demand Drug Release

Abstract

Traditional implanted drug delivery systems cannot easily change their release profile in real time to respond to physiological changes. Here we present a microfluidic aqueous two‐phase system to generate microcapsules that can release drugs on demand as triggered by focused ultrasound (FUS). The biphasic microcapsules are made of hydrogels with an outer phase of mixed molecular weight (MW) poly(ethylene glycol) diacrylate that mitigates premature payload release and an inner phase of high MW dextran with payload that breaks down in response to FUS. Compound release from microcapsules could be triggered as desired; 0.4 μg of payload was released across 16 on‐demand steps over days. We detected broadband acoustic signals amidst low heating, suggesting inertial cavitation as a key mechanism for payload release. Overall, FUS‐responsive microcapsules are a biocompatible and wirelessly triggerable structure for on‐demand drug delivery over days to weeks.

Document Details

Document Type
Pub Defense Publication
Publication Date
Mar 16, 2022
Source ID
10.1002/anie.202116515

Entities

People

  • Kelia A Human
  • Margaret A. Jakus
  • Parag V. Chitnis
  • Rachel D. Field
  • Samuel K Sia
  • Xiaoyu Chen
  • Xuanhe Zhao

Organizations

  • Columbia University
  • Defense Advanced Research Projects Agency
  • George Mason University
  • Massachusetts Institute of Technology
  • National Center for Advancing Translational Sciences

Tags

Readers

  • Chemistry (specifically Chemical Fluorescence)
  • Systems Analysis and Design
  • Trauma Surgery or Emergency Medicine.