Frontal polymerization accelerated by continuous conductive elements

Abstract

Frontal polymerization (FP), a propagating reaction wave driven by exothermic polymerization, is increasingly considered for the rapid fabrication of fiber‐reinforced composites. However, the effect of the fibers on the FP reaction has not yet been explored. In this contribution, we demonstrate that thermally conductive continuous elements accelerate FP using an experimental model system and finite‐element‐based numerical simulations. Furthermore, the degree of acceleration is shown to be affected by the amount of available monomer in the system. These results suggest that thermally conductive carbon fiber reinforcement may facilitate FP for composite manufacturing. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47418.

Document Details

Document Type
Pub Defense Publication
Publication Date
Dec 29, 2018
Source ID
10.1002/app.47418

Entities

People

  • Elyas Goli
  • Emmy L. Pruitt
  • Harshit Agarwal
  • Ian D. Robertson
  • Jeffrey S. Moore
  • Joshua M Grolman
  • Philippe H Geubelle

Organizations

  • Air Force Office of Scientific Research
  • Office of Naval Research
  • United States Department of Defense
  • University of Illinois Urbana–Champaign

Tags

Fields of Study

  • Materials science

Readers

  • Combustion Dynamics and Shock Wave Physics.
  • Polymer Science and Technology
  • Reinforced Composite Materials