Small Cation‐Based High‐Performance Energetic Nitraminofurazanates

Abstract

Large nitramino‐substituted furazan anions were combined with small cations (hydroxylammonium, hydrazinium, and ammonium) to form a series of energetic salts that was fully characterized. The structures of several of the compounds (1 a, 2 a, 3 a, and 4 a) were further confirmed by single‐crystal X‐ray diffraction. Based on their physiochemical properties, such as density, thermal stability, and sensitivity, together with the calculated detonation properties, it was found that they exhibit good detonation performance and have potential application as high‐energy‐density materials.

Document Details

Document Type
Pub Defense Publication
Publication Date
Jun 29, 2016
Source ID
10.1002/chem.201602171

Entities

People

  • Chunlin He
  • Damon A. Parrish
  • Jean'ne Shreeve
  • Lauren A. Mitchell
  • Yongxing Tang

Organizations

  • Defense Threat Reduction Agency
  • Office of Naval Research
  • United States Naval Research Laboratory
  • University of Idaho
  • University of Minnesota

Tags

Fields of Study

  • Chemistry

Readers

  • Materials Science and Engineering.
  • Organic Chemistry
  • Rocket Propulsion.