Implications of Exceptional Material Kinetics on Thermochemical Fuel Production Rates
Abstract
Production of chemical fuels by solar‐driven thermochemical cycling has recently generated significant interest for its potential as a highly efficient method of storing solar energy. Of particular interest is the thermochemical process using non‐stoichiometric oxides, such as ceria. In this process a reactive oxide is cyclically exposed to an inert gas, typically at 1500 °C to induce the partial reduction of the oxide, and then exposed to an oxidizing gas of either H2O or CO2 at a temperature between 800–1500 °C to oxidize the oxide and release H2 or CO. Conventional wisdom has held that material kinetics limit the fuel production rates. Herein we demonstrate that, instead, at 1500 °C the rates of both reduction and oxidation of ceria, and hence also the global fuel production rate, are limited only by thermodynamic considerations for any reasonable set of operating conditions. Thus, in terms of materials design, significant room exists for sacrificing material kinetics in favor of thermodynamic characteristics.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Feb 23, 2016
- Source ID
- 10.1002/ente.201500506
Entities
People
- Chih‐kai Yang
- Christopher J. Kucharczyk
- Michael J. Ignatowich
- Sossina M. Haile
- Timothy C. Davenport
Organizations
- California Institute of Technology
- Defense Advanced Research Projects Agency
- National Science Foundation
- Northwestern University
- United States Department of Energy