Ultra‐low Mass Sputtered and Conventional Catalyst Layers on Plasma‐etched Nafion for PEMFC Applications

Abstract

This paper presents performance results for the use of plasma‐etched Nafion membranes to suppress polarization losses in proton exchange membrane fuel cells (PEMFCs) configured from 0.1 mg cm−2 conventional Pt/C dispersion and 0.02 mg cm−2 ultra‐thin sputter‐deposited Pt catalyst layers. Four MEA configurations, namely, etched membrane‐conventional electrode, pristine membrane‐conventional electrode, etched membrane‐sputter electrode, and pristine membrane‐sputter electrode cells were explored, and their respective maximum power densities were ∼514.6, 417.9, 170.1 and 138.3 mW cm−2. The results demonstrated that independent of MEA fabrication approach, cells with O2 plasma treated membranes had reduced ohmic resistances and delivered superior performance over their pristine counterparts, validating the utility of membrane etching for achieving improved PEMFC performance.

Document Details

Document Type
Pub Defense Publication
Publication Date
Oct 25, 2017
Source ID
10.1002/fuce.201600183

Entities

People

  • A. Omosebi
  • R. S. Besser

Organizations

  • Army Research Office
  • Stevens Institute of Technology
  • United States Department of Energy
  • University of Kentucky

Tags

Fields of Study

  • Materials science

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Nanocomposite Materials Science
  • Thin Film Deposition Science.

Technology Areas

  • Biotechnology