Zipping Polymers into Nanoparticles via Intrachain Alternating Radical Copolymerization
Abstract
The synthesis of single‐chain nanoparticles (SCNP) via the intrachain radical homopolymerization and alternating copolymerization of pendant styrene or stilbene units is reported. In the presence of a radical initiator, styrene‐functionalized polymers undergo intrachain cross‐linking to form SCNP; however, when an electron deficient monomer such as maleic anhydride is added, interchain coupling occurs. For the stilbene‐functionalized polymer, no homopolymerization of pendant stilbene units is observed, but copolymerization initiated in the presence of maleic anhydride or N‐ethyl maleimide results in nanoparticle formation. Fluorescent SCNP are synthesized using N‐(1‐pyrene)maleimide. Stilbene is known to undergo alternating copolymerization with these electron‐deficient monomers, providing a new method for synthesizing cross‐linked particles with simple alternating sequences while simultaneously installing functionality and tuning the particle size and density. image
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Dec 09, 2015
- Source ID
- 10.1002/macp.201500355
Entities
People
- Christopher K. Lyon
- Ellen O. Hill
- Erik B. Berda
Organizations
- Army Research Office
- National Aeronautics and Space Administration
- University of New Hampshire