Modeling of PEG Hydrogel Membranes for Biomedical Applications

Abstract

A mathematical model has been developed for surface‐initiated photopolymerization of PEG‐DA forming cross‐linked hydrogel membranes on the surface of a substrate. The existing model was extended to apply the NF technique, which made it possible to describe the progression of photopolymerization through gelation, and to calculate gelation time, cross‐link density of the gel and soluble phases. The model provides a tool for understanding and studying the kinetics of interfacial photopolymerization reactions, which are important in processes such as cell encapsulation by hydrogel membranes formed through free radical photopolymerization. It will also be useful for applications in tissue engineering, where protein gradients are required for optimizing engineered tissue formation.

Document Details

Document Type
Pub Defense Publication
Publication Date
Jul 08, 2009
Source ID
10.1002/mren.200900005

Entities

People

  • Fouad Teymour
  • Seda Kizilel
  • Víctor H. Pérez‐luna

Organizations

  • Office of Naval Research

Tags

Fields of Study

  • Chemistry

Readers

  • Chemistry (specifically Chemical Fluorescence)
  • Molecular and Cellular Biochemistry
  • Polymer Science and Engineering.

Technology Areas

  • Biotechnology