Composition‐dependent underwater adhesion of catechol‐bearing hydrogels

Abstract

Interfacial adhesion‐mediated transfer printing processes can integrate functional electronic microstructures with polymeric substrates that are bendable and stretchable. Transfer printing has also been extended to catechol‐bearing adhesive hydrogels. This study presents indentation adhesion tests between catechol‐bearing hydrogel substrates with catechol concentrations varying from 0 to 10% (mol/mol) and thin‐film materials commonly used in microelectronic fabrication including polymers, noble metals and oxides. The results indicate that the interfacial adhesion of catechol‐bearing hydrogels is positively correlated with the concentration of catechol‐bearing monomers as well as the retraction velocity during transfer printing. This study can inform transfer printing processes for microfabricated structures to compliant hydrated substrates such as hygroscopic monomers, mesoporous polymer networks and hydrogels. © 2016 Society of Chemical Industry

Document Details

Document Type
Pub Defense Publication
Publication Date
Sep 08, 2016
Source ID
10.1002/pi.5246

Entities

People

  • Christopher J. Bettinger
  • Hangjun Ding
  • Haosheng Wu
  • Jingsi Zhao
  • Metin Sitti
  • Veikko Sariola

Organizations

  • Aalto University
  • Carnegie Mellon University
  • Defense Advanced Research Projects Agency
  • Jenny and Antti Wihuri Foundation
  • Max Planck Institute for Intelligent Systems
  • National Institutes of Health
  • National Science Foundation
  • Research Council of Finland

Tags

Fields of Study

  • Materials science

Readers

  • Nanocomposite Materials Science
  • Surface Coatings Technology.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene