On the use of graphene to improve the performance of concentrator III‐V multijunction solar cells

Abstract

Graphene has been intensively studied in photovoltaics focusing on emerging solar cells based on thin films, dye‐sensitized solar cells, quantum dots, nanowires, and so forth. However, the typical efficiency of these solar cells incorporating graphene is below 16%. Therefore, the photovoltaic potential of graphene has not yet been shown. In this work, the use of graphene for concentration applications on III‐V multijunction solar cells, which indeed are the solar cells with the highest efficiency, is demonstrated. First, a wide optoelectronic characterization of graphene layers is carried out. Then, the graphene layer is incorporated onto triple‐junction solar cells, which decreases their series resistance by 35% (relative), leading to an increase in fill factor of 4% (absolute) at concentrations of 1000 suns. Simultaneously, the optical absorption of graphene produces a relative short‐circuit current density decrease in the range of 0% to 1.8%. As a result, an absolute efficiency improvement close to 1% at concentrations of 1000 suns was achieved with respect to triple‐junction solar cells without graphene. The impact of incorporating one and two graphene monolayers is also evaluated.

Document Details

Document Type
Pub Defense Publication
Publication Date
Nov 03, 2019
Source ID
10.1002/pip.3207

Entities

People

  • Andrew Johnson
  • Carlos Algora
  • Ignacio Rey-Stolle
  • Iván Garcia
  • Iván Lombardero
  • Laura Barrutia
  • Maria Mercedes Gabas Perez
  • Mario Ochoa
  • Tomás Palacios

Organizations

  • Air Force Office of Scientific Research
  • Massachusetts Institute of Technology
  • Ministry of Economy, Industry and Competitiveness
  • Ministry of Education, Culture and Sport
  • Ministry of Science of Spain
  • National Science Foundation
  • National Stroke Foundation
  • Universidad de Málaga

Tags

Fields of Study

  • Physics

Readers

  • Quantum Dot Semiconductor Device Photonics and Graphene Optoelectronic Materials and THz Physics.
  • Solar Photovoltaics and Thermoelectric Devices.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene
  • Quantum Computing