Modeling of displacement damage in an ion‐beam‐modified perfluorosulfonate ionomer

Abstract

A Monte Carlo simulation has been used to model the effects of medium‐energy ion‐beam modification of Nafion. With typical ion energies of 100–200 keV, the treatment affects the outer 0.5–2‐μm surface layer. An equation has been developed for predicting the expected range of implantation as a function of the ion energy and atomic number. The expected range of displacement damage due to the ion beam can similarly be described over the whole parameter range of interest with a double logarithmic fit. A full characterization of the distributions with their first four statistical moments is also presented. The quantitative description of the profiles obtained is useful for the rational design of an ion‐beam treatment for the preparation of integrally skinned membranes. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 1343–1350, 2004

Document Details

Document Type
Pub Defense Publication
Publication Date
Feb 24, 2004
Source ID
10.1002/polb.20010

Entities

People

  • Eugene Wilusz
  • Frank E Karasz
  • Zoltan A. Fekete

Organizations

  • Air Force Office of Scientific Research

Tags

Fields of Study

  • Physics

Readers

  • Calculus or Mathematical Analysis
  • Polymer Science and Technology
  • Structural Health Monitoring of Composite Structures.