Nanoscale interfibrillar adhesion in UHMWPE fibers
Abstract
The goal of this research is to quantify the fibrillar adhesive energy in ultra‐high molecular weight polyethylene fibers, characteristic of nanoscale fibril interactions. Quantification of these energies is vital to the understanding of fibrillar deformation mechanisms that have been shown to play an important role in fiber performance. This is achieved through the development and implementation of a nanosplitting technique developed through the use of AFM‐enabled nanoindentation. This technique allows the quantification of nanoscale adhesive energies through careful monitoring of load and unload curves as well as examination of the residual split through high‐resolution AFM images. Results indicate that the average nanoscale fibril adhesive energy is over 3 times larger than the energy expected from van der Waals interactions alone. This indicates that a significant degree of physical interactions exist between fibrils, beyond van der Waals interactions, in the form of tie‐molecules, fibrillar network junctions, and bridging lamellar crystals. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2018, 56, 391–401
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Dec 19, 2017
- Source ID
- 10.1002/polb.24552
Entities
People
- John W. Gillespie Jr.
- Joseph M. Deitzel
- Kenneth E Strawhecker
- Preston B. McDaniel
Organizations
- United States Army Research Laboratory
- University of Delaware