Formation and Characterization of Heavy Alkali and Silver Salts of the 4‐Nitro‐pyrazolo‐(3,4‐c)‐furazan‐5‐N‐oxide Anion
Abstract
The nitration of 3‐amino‐4‐chloro‐oximidofurazan resulted in the formation of the unexpected anionic heterocycle 4‐nitro‐pyrazolo‐(3,4,c)‐furazan‐5‐N‐oxide. Various experiments such as changing the reactants, oxidation or methylation were attempted to elucidate the reaction conditions and mechanism. The heavier alkali and silver salts of the above‐mentioned heterocycle were isolated. The salts were characterized and investigated by means of NMR, vibrational spectroscopy, X‐ray diffraction and energetic properties.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Sep 18, 2017
- Source ID
- 10.1002/prep.201700170
Entities
People
- Burkhard Krumm
- Thomas M. Klapötke
- Tobias S. Hermann
Organizations
- Ludwig-Maximilians-Universität München
- Office of Naval Research