Nitrate Salt Based Melt Cast Materials

Abstract

Three new low melting compositions have been developed based on the ingredients amino‐1,2,4‐triazolium nitrate, 3,5‐diamino‐1,2,4‐triazolium nitrate and ammonium nitrate, to create the formulation AAD, in addition to mixtures comprising guanidinium 5‐amino‐tetrazolate and ammonium nitrate in either a 1 : 3 or 1 : 6 mole ratio (GAN13 and GAN16 respectively). The materials melt in the range of 95–100 °C and do not begin to decompose until >195 °C. The formulations are insensitive to impact, spark and friction and were calculated to show promising explosive performance properties (VD=8.78–9.0 km/s, PCJ=28.4–30.6 GPa). HMX mixtures of AAD, GAN13 and GAN16 were also prepared and these materials were characterized with respect to their safety and performance as well.

Document Details

Document Type
Pub Defense Publication
Publication Date
Oct 24, 2017
Source ID
10.1002/prep.201700183

Entities

People

  • David E Chavez
  • Elizabeth G. Francois
  • Patrick R. Bowden
  • Philip W Leonard

Organizations

  • Los Alamos National Laboratory
  • United States Army Research Laboratory

Tags

Fields of Study

  • Materials science

Readers

  • Agricultural Chemistry/Soil Science
  • Rocket Propulsion.
  • Semiconductor Device Technology