Experimental Vapor Pressures of Hexahydro‐1,3,5‐trinitro‐1,3,5‐triazine (RDX) and Hexahydro‐1,3,5‐trinitroso‐1,3,5‐triazine (TNX)

Abstract

In this work experimental vapor pressures of hexahydro‐1,3,5‐trinitro‐1,3,5‐triazine (RDX) and hexahydro‐1,3,5‐trinitroso‐1,3,5‐triazine (TNX) were measured with transpiration method. Corresponding enthalpies of sublimation were determined to be (130.9±2.1) kJ mol−1 and (108.1±1.6) kJ mol−1, respectively. Along with the experimental data fitting equations are reported and p‐T data extrapolated to 298.15 K to be 0.71 μPa for RDX and 823 μPa for TNX.

Document Details

Document Type
Pub Defense Publication
Publication Date
Jul 28, 2020
Source ID
10.1002/prep.202000098

Entities

People

  • Greta Bikelytė
  • Martin A. C. Härtel
  • Thomas M. Klapötke

Organizations

  • German Academic Exchange Service
  • Ludwig-Maximilians-Universität München
  • Office of Naval Research
  • Strategic Environmental Research and Development Program

Tags

Fields of Study

  • Chemistry

Readers

  • Agricultural Chemistry/Soil Science
  • Electrochemical Engineering/ Fuel Cell Technologies
  • Spectroscopy.