Synthesis and Characterization of the Energetic 3‐Azido‐5‐amino‐6‐nitro‐1,2,4‐triazine
Abstract
The reaction of diazotetrazole with nitroacetonitrile led to the isolation of the simple 1,2,4‐triazine‐based energetic 3‐azido‐5‐amino‐6‐nitro‐1,2,4‐triazine. It and related compounds were chemically characterized by NMR, IR, and single‐crystal X‐ray crystallography. Their energetic sensitivities (impact, friction) were experimentally determined and energetic performances calculated. The ability of 3‐azido‐5‐amino‐6‐nitro‐1,2,4‐triazine to form N‐oxides was also studied.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Jan 12, 2021
- Source ID
- 10.1002/prep.202000136
Entities
People
- Davin G Piercey
- Edward F. C. Byrd
- Matthias Zeller
- Shannon E. Creegan
Organizations
- National Science Foundation
- Office of Naval Research
- Purdue University
- United States Army Research Laboratory