Laser Fluence Dependence of the Electrical Properties of MoO2 Formed by High Repetition Femtosecond Laser Pulses

Abstract

Molybdenum oxides have gained attention in the last few years due to their vast variety of polymorphs. These materials relate to technological applications in several devices to exploit their chromic and electrical features, among others. Molybdenum oxide (MoO2 and Mo4O11) tracks are obtained in molybdenum thin films, deposited on glass substrates, by a previously reported (by our research group) optical technique based on femtosecond pulses from a Ti:sapphire laser oscillator. The present work reports on both the electrical resistance and resistivity of MoO2 tracks as a function of the per pulse laser fluence (Fp) used for the oxide synthesis. It is found that the electrical resistance, as well as the resistivity, of the MoO2 tracks drops as the delivered laser fluence is increased. The resistivity was determined to drop from 1.7 × 10−3 Ω cm to 5 × 10−4 Ω cm. This result agrees well with resistivity measurements reported in the literature for MoO2 nanosheets and films, respectively. This is explained by the fact that at low laser fluence the MoO2 forms a very thin surface layer, while for high laser fluences the MoO2 will get thick.

Document Details

Document Type
Pub Defense Publication
Publication Date
Sep 16, 2018
Source ID
10.1002/pssa.201800226

Entities

People

  • Alejandro Esparza‐garcia
  • Israel Pérez
  • J. Apolinar Reynoso‐hernandez
  • M. Carmen Maya‐sanchez
  • Marco Camacho‐lopez
  • Miroslava Cano‐lara

Organizations

  • Air Force Office of Scientific Research
  • Ensenada Center for Scientific Research and Higher Education
  • National Autonomous University of Mexico
  • Universidad Autónoma del Estado de México

Tags

Fields of Study

  • Materials science

Readers

  • Optical Physics and Photonics.
  • Polymer Science and Engineering.
  • Pulsed Power and Plasma Physics.

Technology Areas

  • Directed Energy
  • Directed Energy - Pulsed-Laser Deposition