Electric Field Polarized Fe−N Functionalized Graphene Oxide Nanosheet Catalyst for Efficient Oxygen Reduction Reaction

Abstract

Low‐cost noble‐metal‐free electrocatalysts for oxygen reduction reaction (ORR) are useful for future energy storage and conversion devices, and other technologies. In this work, iron (Fe)‐nitrogen (N) functionalized graphene oxide (Fe−N−GO) nanosheets have been synthesized and studied for ORR properties in alkaline solution. We utilized a multi‐layer/multi‐polarization method to study the DC electric field polarization effect on the electrocatalytic properties of the Fe−N−GO catalyst. The poling effect with DC electric field was created on the catalyst ink drop‐casted on a polished glassy carbon working electrode, resulting in more compact electrocatalyst electrode. Compared to the commercial Pt/C catalyst, the polarized Fe−N−GO catalyst exhibited similar ORR catalytic activity along with superior stability in alkaline media.

Document Details

Document Type
Pub Defense Publication
Publication Date
Jul 11, 2022
Source ID
10.1002/slct.202200616

Entities

People

  • Guang–Lin Zhao
  • Jiaxin Xia
  • Peter Adamaquaye
  • Rong Zhao

Organizations

  • Army Research Office
  • National Science Foundation

Tags

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Materials Science and Engineering.
  • Nanoscale Plasmonic Nanotechnology

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene