Fading Mechanisms and Voltage Hysteresis in FeF2–NiF2 Solid Solution Cathodes for Lithium and Lithium‐Ion Batteries
Abstract
The rapid development of ultrahigh‐capacity alloying or conversion‐type anodes in rechargeable lithium (Li)‐ion batteries calls for matching cathodes for next‐generation energy storage devices. The high volumetric and gravimetric capacities, low cost, and abundance of iron (Fe) make conversion‐type iron fluoride (FeF2 and FeF3)‐based cathodes extremely promising candidates for high specific energy cells. Here, the substantial boost in the capacity of FeF2 achieved with the addition of NiF2 is reported. A systematic study of a series of FeF2–NiF2 solid solution cathodes with precisely controlled morphology and composition reveals that the presence of Ni may undesirably accelerate capacity fading. Using a powerful combination of state‐of‐the‐art analytical techniques in combination with the density functional theory calculations, fundamental mechanisms responsible for such a behavior are uncovered. The unique insights reported in this study highlight the importance of careful selection of metals and electrolytes for optimizing electrochemical properties of metal fluoride cathodes.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Jan 15, 2019
- Source ID
- 10.1002/smll.201804670
Entities
People
- Alexandre Magasinski
- Doyoub Kim
- Gleb Yushin
- Oleg Borodin
- Qiao Huang
- Travis P. Pollard
- Xiaolei Ren
Organizations
- Army Research Office
- Central South University
- China Scholarship Council
- Chongqing University
- Georgia Tech
- United States Army Research Laboratory