Selected Nitrocarbamates of Glycerine & Co. and the First Acetylene Derivative
Abstract
A simple two step synthesis route for the preparation of several energetic multivalent nitrocarbamates of easily available alcohols is presented. The carbamates were obtained by the reaction of the alcohols and the reactive reagent chlorosulfonyl isocyanate (CSI) with subsequent aqueous work‐up. The nitration of the carbamates was performed with mixed acid (nitric and sulfuric acid). The thermal stabilities were explored by using differential scanning calorimetry and the energies of formation were calculated on the CBS‐4M level of theory, as well as several detonation and propulsion parameters for the application as energetic materials. All compounds were fully characterized and discussed in addition with single X‐ray diffraction.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Dec 22, 2015
- Source ID
- 10.1002/zaac.201500795
Entities
People
- Burkhard Krumm
- Quirin J. Axthammer
- Thomas M. Klapötke
Organizations
- Office of Naval Research
- United States Army Armament Research, Development and Engineering Center
- United States Army Research Laboratory