Synthesis and Characterization of Tetrahedral Zinc(II) Complexes with 3, 6,7‐Triamino‐7H‐[1, 2,4]triazolo[4, 3‐b][1, 2,4]triazole as Nitrogen‐Rich Ligand
Abstract
Triaminotriazolotriazole (TATOT) was used as a nitrogen‐rich ligand for the formation of the energetic ZnII complexes [ZnCl2(TATOT)2]·H2O (2), [Zn(H2O)(TATOT)3](NO3)2·2H2O (3), and [Zn(TATOT)4](ClO4)2·2H2O (4). The zinc species were prepared in a straightforward and inexpensive synthesis. The complexes 2–4 were structurally characterized using X‐ray diffraction. Additionally, the compounds were characterized using elemental analysis and infrared (IR) spectroscopy. Finally, the sensitivities toward thermal and mechanical stimuli were determined by differential thermal analysis (DTA) and BAM (Bundesanstalt für Materialforschung und ‐prüfung) methods.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Feb 29, 2016
- Source ID
- 10.1002/zaac.201600006
Entities
People
- Jörg Stierstorfer
- Norbert Szimhardt
- Philipp C. Schmid
- Thomas M. Klapötke
Organizations
- Office of Naval Research
- United States Army Armament Research, Development and Engineering Center
- United States Army Research Laboratory