Hierarchical Eutectoid Nano-lamellar Decomposition in an Al0.3CoFeNi Complex Concentrated Alloy

Abstract

This paper reports a novel eutectoid nano-lamellar (FCC + L12)/(BCC + B2) microstructure that has been discovered in a relatively simple Al0.3CoFeNi high entropy alloy (HEA) or complex concentrated alloy (CCA). This novel eutectoid nano-lamellar microstructure presumably results from the complex interplay between Al-mediated lattice distortion (due to its larger atomic radius) in a face-centered cubic (FCC) CoFeNi solid solution, and a chemical ordering tendency leading to precipitation of ordered phases such as L12 and B2. This eutectoid microstructure is a result of solid-state decomposition of the FCC matrix and therefore distinct from the commonly reported eutectic microstructure in HEAs which results from solidification. This novel nano-lamellar microstructure exhibits a tensile yield strength of 1074 MPa with a reasonable ductility of 8%. The same alloy can be tuned to form a more damage-tolerant FCC + B2 microstructure, retaining high tensile yield stress (~900 MPa) with appreciable tensile ductility (>20%), via annealing at 700 °C. Such tunability of microstructures with dramatically different mechanical properties can be effectively engineered in the same CCA, by exploiting the complex interplay between ordering tendencies and lattice distortion.

Document Details

Document Type
Pub Defense Publication
Publication Date
Mar 16, 2020
Source ID
10.1038/s41598-020-61538-6

Entities

People

  • Abhinav Jagetia
  • Bharat Gwalani
  • Rajarshi Banerjee
  • Sriswaroop Dasari
  • Stéphane Gorsse
  • Vishal Soni

Organizations

  • Air Force Office of Scientific Research

Tags

Fields of Study

  • Materials science

Readers

  • Nanocomposite Materials Science
  • Powder metallurgy of Titanium alloys.