The mechanism of the Pd-catalyzed formation of coumarins: a theoretical study

Abstract

The formation of coumarins via the Pd-catalyzed intramolecular hydroarylation of the C–C triple bond is shown to proceed via the concerted metalation–deprotonation (CMD) mechanism.

Document Details

Document Type
Pub Defense Publication
Publication Date
Jan 01, 2015
Source ID
10.1039/c4cp03418j

Entities

People

  • Anastassia N. Alexandrova
  • S. Nedd

Organizations

  • California NanoSystems Institute
  • Defense Advanced Research Projects Agency
  • United States Army
  • University of California
  • Yusuf Hamied Department of Chemistry

Tags

Fields of Study

  • Chemistry