Energies and structures in biradical chemistry from the parametric two-electron reduced-density matrix method: applications to the benzene and cyclobutadiene biradicals

Abstract

The treatment of biradical chemistry presents a challenge for electronic structure theory, especially single-reference methods, as it requires the description of varying degrees and kinds of electron correlation.

Document Details

Document Type
Pub Defense Publication
Publication Date
Jan 01, 2015
Source ID
10.1039/c5cp01310k

Entities

People

  • Alison L. Mcmanus
  • David A Mazziotti
  • Erik P. Hoy

Organizations

  • Army Research Office
  • James Franck Institute
  • National Science Foundation
  • United States Army
  • University of Chicago
  • W. M. Keck Foundation

Tags

Fields of Study

  • Chemistry

Readers

  • Chemistry (specifically Chemical Fluorescence)
  • Computational Modeling and Simulation
  • Quantum Chemistry

Technology Areas

  • Microelectronics