Dioxygen binding at a four-coordinate cobaltous porphyrin site in a metal–organic framework: structural, EPR, and O2adsorption analysis

Abstract

The binding of O2at a four-coordinate cobaltous porphyrin site within a metal–organic framework is examined through single-crystal X-ray diffraction, EPR spectroscopy, and O2adsorption measurements.

Document Details

Document Type
Pub Defense Publication
Publication Date
Jan 01, 2016
Source ID
10.1039/c5qi00275c

Entities

People

  • Audrey T. Gallagher
  • James P S Walsh
  • Jarad A Mason
  • Jesse G. Park
  • John S. Anderson
  • Margaret L. Kelty
  • Shenell L. Collins
  • T. David Harris

Organizations

  • Air Force Office of Scientific Research
  • Army Research Office
  • Northwestern University
  • United States Army
  • Yusuf Hamied Department of Chemistry

Tags

Readers

  • Organic Chemistry