Synthesis and investigation of donor–porphyrin–acceptor triads with long-lived photo-induced charge-separate states
Abstract
The powerful electron donor tetraalkylphenylenediamine (TAPD) facilitates photo-induced electron transfer, even in a frozen solvent at 10 K, generating a long-lived spin-polarized charge separate state which can be observed by EPR.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Jan 01, 2015
- Source ID
- 10.1039/c5sc01830g
Entities
People
- Brendon W. Lovett
- Di Wu
- Harry Anderson
- John J. L. Morton
- Julien B Kelber
- Naitik A. Panjwani
- Rafael Gómez-Bombarelli
Organizations
- Chemistry Research Laboratory, University of Oxford
- Defense Advanced Research Projects Agency
- Engineering and Physical Sciences Research Council
- Harvard University
- London Centre for Nanotechnology
- Scottish Universities Physics Alliance
- United States Army
- University College London
- University of Cambridge
- University of Kentucky
- University of Oxford
- University of St Andrews
- Yusuf Hamied Department of Chemistry