A flexible iron(ii) complex in which zero-field splitting is resistant to structural variation

Abstract

The zero-field splitting parameters D and E in the iron(ii) complex [Fe(C3S5)2]2− are shown to be remarkably resistant to a twist of the inter-ligand dihedral angle (θd) from 90 to 70°.

Document Details

Document Type
Pub Defense Publication
Publication Date
Jan 01, 2016
Source ID
10.1039/c5sc02477c

Entities

People

  • Danna E. Freedman
  • Joseph M. Zadrozny
  • Samuel M Greer
  • Stephen Hill

Organizations

  • Air Force Office of Scientific Research
  • Division of Graduate Education
  • Division of Materials Research
  • Florida State University
  • Illinois Department of Commerce and Economic Opportunity
  • National High Magnetic Field Laboratory
  • Northwestern University
  • United States Army
  • Yusuf Hamied Department of Chemistry

Tags

Fields of Study

  • Chemistry

Readers

  • Aerodynamics/Aeronautics.
  • Molecular Photonics/Laser Physics
  • Organic Chemistry