Two-coordinate group 14 element(ii) hydrides as reagents for the facile, and sometimes reversible, hydrogermylation/hydrostannylation of unactivated alkenes and alkynes
Abstract
The ambient temperature hydrometallations of a variety of unactivated alkene and alkyne substrates using two-coordinate hydrido-tetrylenes, :E(H)(L†) (E = Ge or Sn; L† = extremely bulky amide), are reported.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Jan 01, 2015
- Source ID
- 10.1039/c5sc03376d
Entities
People
- Cameron Jones
- Gernot Frenking
- Markus Hermann
- Terrance J. Hadlington
Organizations
- Australian Research Council
- German Research Foundation
- Monash University
- United States Air Force
- University of Marburg